The asymmetric intramolecular Heck reaction in natural product total synthesis.
نویسندگان
چکیده
منابع مشابه
Access to enantioenriched 2,3- and 2,5-dihydrofurans with a fully substituted C2 stereocenter by Pd-catalyzed asymmetric intermolecular Heck reaction† †Electronic supplementary information (ESI) available: Experimental procedures, characterization of all new compounds, VCD studies and spectral data. See DOI: 10.1039/c5sc01460c Click here for additional data file.
During the past decades, building on the seminal contributions of Overman and Shibasaki, the asymmetric intramolecular Heck reaction has been successfully applied in natural product synthesis to install tertiary and quaternary stereocenters. In stark contrast, the intermolecular version of this asymmetric transformation has not reached the same level of development and its synthetic utility rem...
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ورودعنوان ژورنال:
- Chemical reviews
دوره 103 8 شماره
صفحات -
تاریخ انتشار 2003